SOx emission levels can be calculated
from coal sulphur content. Ash chemistry and ash content have some
influence, as some absorption of SO2 takes place in the
ash. The level of absorption increases with increasing alkalinity
levels in ash (ie. high levels of CaO, MgO, etc.) and increasing
ash content, however it is unlikely that absorption levels would
ever exceed 10-15% of the total SO2 produced.
SO2 emissions are additive and therefore can be
calculated from the sulphur content of the component coals with any
SO2 absorption onto the ash estimated from the ash
chemistry of the component coals.
SOx emissions may be reduced by direct injection
of a sorbent directly into the furnace chamber and/or by flue gas
desulphurisation
(FGD) systems attached to the back end of the
boiler. All FGD systems involve intimately mixing the SOx emissions
with an absorbing chemically reactive material, which converts them
into a solid or liquid product. This product may have a marketable
value.