Interest in the integrated gasification combined
cycle (IGCC) process is based principally on its potential
environmental benefits. When the gasifier is supplied by oxygen
instead of air, IGCC plant offer the potential to capture
relatively pure carbon dioxide (without nitrogen dilution) that
could then be sequestered to virtually eliminate greenhouse gas
emissions. There are several gasification processes in operation as
well as in development. These can be broadly divided into three
main categories: fixed bed, moving bed (e.g. fluidised bed) and
entrained flow processes. The table below summaries the
typical properties for several gasifiers.
Properties
|
Lurgi Moving Bed
|
Winkler Fluidised Bed
|
Entrained – Phase Gasifiers
|
Koppers -
Totzek
|
Texaco
|
Caking
properties
|
Non-caking to weakly
caking coal
|
Non-caking to medium
caking coal
|
n/a
|
Preferably
non-caking
|
Particle
size
|
Particles between 6 and
40mm required; no fines
|
0–8mm
|
Grinding to 90% < 0.1mm
(bituminous coal) or
80–85% < 0.1mm (lignite)
|
Grinding to 90% < 0.5mm
50% < 0.09mm
|
Ash % db
|
Up to 40%
|
Up to 50%
|
Up to 40%
|
Up to 40%
|
Ash fusion
|
Deformation temperature
above temperature in
combustion zone
|
Deformation temperature
markedly above gasification
temperature
|
Flow temperature below
1500°C
|
Flow temperature below
1300°C
|
Moisture
|
Up to 40%
|
Up to 8%
|
1–2% (bituminous coal) or
8–10% (lignite) before
grinding
|
Equilibrium moisture less
than 4%
|
Sulphur
|
n/a
|
n/a
|
n/a
|
n/a
|
Shatter
index
|
High
|
High
|
n/a
|
n/a
|
HGI
|
n/a
|
|
Greater than 40
|
Greater than 40
|
Rank
|
Lignite - HV bituminous
|
Lignite - HV bituminous
|
All
|
All
|
Volatile
matter
|
n/a
|
n/a
|
High
|
High
|
In IGCC power plants, the coal is gasified and
the off-take gas is combusted in gas turbines to generate
electricity. The hot combustion gases are then passed through
boilers to produce steam for further power generation or other
industrial use. Thermal efficiencies of 45% higher heat value (HHV)
or greater have been achieved in such plant. Several full-scale
demonstration plants are operating commercially in the USA and in
Europe.